Everyone is different, so it's tough to flat out tell you what will work, but:
The split you have lined up there will almost certainly require you to only do 1-3 muscle groups per workout. I would not work any muscle group on all 5 days. Also, You'll want to put heavy leg work on either Monday or Wednesday, to allow a day completely off for recovery. The other day that has a rest day following it may be best suited for triceps and biceps. They will be worked indirectly on whatever day you work chest and back respectively.
In order to increase muscle mass that drastically while dropping fat will require a great diet, with higher protein than most people consume.
Start by figuring your baseline calories, and increasing by about 15%.
Get back to us with specific questions.
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